| Ayr United FC v Newcastle United FC 13/09/1972 | View match | |
| Ayr United FC v Morton FC 16/09/1972 | View match | |
| Arbroath FC v Ayr United FC 23/09/1972 | View match | |
| Newcastle United FC v Ayr United FC 27/09/1972 | £4.50 | |
| Celtic (Glasgow) FC v Ayr United FC 30/09/1972 | View match | |
| Ayr United FC v Partick Thistle FC 07/10/1972 | View match | |
| East Fife FC v Ayr United FC 14/10/1972 | View match | |
| Ayr United FC v Aberdeen FC 21/10/1972 | View match | |
| Dundee United FC v Ayr United FC 28/10/1972 | View match | |
| Ayr United FC v Motherwell FC 04/11/1972 | View match | |
| Heart Of Midlothian (Hearts) v Ayr United FC 11/11/1972 | View match | |
| Ayr United FC v Falkirk FC 18/11/1972 | View match |