| Middlesbrough FC v Roma (AS) 07/03/2006 | £6.50 | |
| Charlton Athletic FC v Middlesbrough FC 23/03/2006 | £5.50 | |
| Basel v Middlesbrough FC 30/03/2006 | £8.50 | |
| Manchester City FC v Middlesbrough FC 02/04/2006 | £5.00 | |
| Middlesbrough FC v Charlton Athletic FC 12/04/2006 | £5.00 | |
| Middlesbrough FC v West Ham United FC 23/04/2006 | £6.50 | |
| Manchester United FC v Middlesbrough FC 01/05/2006 | £3.50 | |
| Fulham FC v Middlesbrough FC 07/05/2006 | £4.00 | |
| Sheffield Wednesday FC v Middlesbrough FC 29/07/2006 | £4.50 | |
| Middlesbrough FC v Chelsea FC 23/08/2006 | £4.50 | |
| Bolton Wanderers FC v Middlesbrough FC 16/09/2006 | £4.20 | |
| Sheffield United FC v Middlesbrough FC 30/09/2006 | £5.50 |