| Plymouth Argyle FC v Huddersfield Town FC 25/03/1966 | View match | |
| Manchester City FC v Plymouth Argyle FC 02/04/1966 | £7.50 | |
| Crystal Palace FC v Plymouth Argyle FC 08/04/1966 | View match | |
| Plymouth Argyle FC v Bristol City FC 09/04/1966 | View match | |
| Plymouth Argyle FC v Crystal Palace FC 11/04/1966 | View match | |
| Wolverhampton Wanderers FC v Plymouth Argyle FC 16/04/1966 | View match | |
| Plymouth Argyle FC v Norwich City FC 23/04/1966 | View match | |
| Bury FC v Plymouth Argyle FC 30/04/1966 | £7.50 | |
| Plymouth Argyle FC v Eintracht Trier (Germany) 02/05/1966 | View match | |
| Plymouth Argyle FC v Southampton FC 07/05/1966 | View match | |
| Bury FC v Plymouth Argyle FC 20/08/1966 | £7.50 | |
| Plymouth Argyle FC v Coventry City FC 24/08/1966 | View match |